By Stal G. Mairanovskii
As our wisdom of the mechanism of electrode approaches raises, it turns into progressively more obvious that the kinetic currents first saw via R. Brdicka and through okay. Wiesner within the 1940's are very greatly encountered. Very many electrode seasoned cesses comprise a chemical level. * this is often actual basically of elec trode procedures that contain natural compounds. accordingly, to appreciate the mechanism of electrode strategies and, specific ly, to properly interpret the result of polarographic investiga tions, it is very important understand the features and relationships controlling the chemical reactions occurring on the electrode floor. as a rule, those reactions are considerably diverse from traditional chemical reactions occurring within the bulk of the answer, because the reactions on the electrodes are frequently laid low with the electrical box of the electrode and the adsorption of the par ticipating compounds . the truth that hydrogen ions often participate in the electro chemical aid of natural compounds makes attainable using electrochemical tools, relatively polarography, for the examine of protolytic reactions. those reactions play a tremendous position in natural chemistry: nearly all of reactions of natural compounds in ideas struggle through a degree during which a hydrogen ion is got rid of or additional (see, for instance, [1, 2]). hence, the polarographic learn of protolytic reactions can provide a lot very important details to theoretical natural chemistry.